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Azabora[5]helicene Charge‐Transfer Dyes Show Efficient and Spectrally Variable Circularly Polarized Luminescence
Author(s) -
Domínguez Zoe,
LópezRodríguez Rocío,
Álvarez Eleuterio,
Abbate Sergio,
Longhi Giovanna,
Pischel Uwe,
Ros Abel
Publication year - 2018
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201801908
Subject(s) - helicene , stokes shift , enantiopure drug , luminescence , circular dichroism , chemistry , photochemistry , circular polarization , toluene , charge (physics) , wavelength , crystallography , molecular physics , materials science , molecule , optoelectronics , physics , optics , organic chemistry , quantum mechanics , microstrip , enantioselective synthesis , catalysis
Three helicenes based on a borylated arylisoquinoline skeleton have been prepared in their enantiopure forms and characterized with respect to their photophysical properties, including the use of chiroptical spectroscopies. The dyes show varying charge‐transfer characteristics and efficient emission (quantum yields between 0.13 and 0.30, in toluene), which is governed by the electron‐donor substitution ( p ‐MeO‐phenyl, p ‐Me 2 N‐phenyl) at the helicene. Marked differences in the emission wavelength and Stokes shift are observed, with the dimethylamino‐substituted derivative emitting most red‐shifted (maximum at ca. 590 nm) and displaying the highest Stokes shift (ca. 6000 cm −1 ) in toluene. The helicenes show electronic circular dichroism (ECD) and significant circularly polarized luminescence (CPL) with dissymmetry factors of up to 3.5×10 −3 . The sign of the ECD band corresponding to the first transition and of the CPL spectrum depend sensibly on the electron‐donor substitution.