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Hydroxylamine Derivatives as Nitrogen‐Radical Precursors in Visible‐Light Photochemistry
Author(s) -
Davies Jacob,
Morcillo Sara P.,
Douglas James J.,
Leonori Daniele
Publication year - 2018
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201801655
Subject(s) - hydroxylamine , photochemistry , chemistry , visible spectrum , nitrogen , molecule , redox , organic chemistry , materials science , optoelectronics
In recent years, hydroxylamines derivatives have been exploited as nitrogen‐radical precursors in visible‐light photochemistry. Their ability to serve as electrophores in redox chemistry has propelled the development of many novel transformations. Fundamental mechanistic aspects as well as the importance in the preparation of nitrogen‐containing molecules will be highlighted.