Premium
Cover Feature: Magnetic Slow Relaxation in a Metal–Organic Framework Made of Chains of Ferromagnetically Coupled Single‐Molecule Magnets (Chem. Eur. J. 27/2018)
Author(s) -
Huang Gang,
FernandezGarcia Guglielmo,
Badiane Insa,
Camarra Magatte,
Freslon Stéphane,
Guillou Olivier,
Daiguebonne Carole,
Totti Federico,
Cador Olivier,
Guizouarn Thierry,
Le Guennic Boris,
Bernot Kevin
Publication year - 2018
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201801396
Subject(s) - magnet , ferromagnetism , metal organic framework , cover (algebra) , relaxation (psychology) , coupling (piping) , molecule , condensed matter physics , materials science , metal , inductive coupling , molecular magnets , feature (linguistics) , chemical physics , chemistry , crystallography , physics , adsorption , magnetization , engineering , mechanical engineering , magnetic field , quantum mechanics , metallurgy , organic chemistry , linguistics , philosophy , psychology , social psychology
Ferromagnetic interactions induced by metal—organic framework (MOF) architecture turn a poor single‐molecule magnet (SMM) into a slow relaxing material. The MOF is made of nine‐coordinated Dy III magnetic building blocks (MBBs) with poor intrinsic SMM behavior. However, the MOF architecture constrains the MBBs in a one‐dimensional structure that induces a ferromagnetic coupling between them. More information can be found in the Full Paper by B. Le Guennic, K. Bernot et al. on page 6983.