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Bromo‐ and Polybromoantimonates(V): Structural and Theoretical Studies of Hybrid Halogen‐Rich Halometalate Frameworks
Author(s) -
Adonin Sergey A.,
Bondarenko Mikhail A.,
Abramov Pavel A.,
Novikov Alexander S.,
Plyusnin Pavel E.,
Sokolov Maxim N.,
Fedin Vladimir P.
Publication year - 2018
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201801338
Subject(s) - thermogravimetric analysis , halogen , bromide , supramolecular chemistry , chemistry , computational chemistry , crystallography , materials science , inorganic chemistry , crystal structure , organic chemistry , alkyl
Cation‐dependent reactions “[SbBr 6 ] 3− +Br 2 +HBr+CationBr x ” result in the formation of bromide/polybromide complexes with zero‐, one‐, two‐, or three‐dimensional supramolecular frameworks and different Br/Sb ratios (up to 11). Seven new compounds representing six structural types were characterized by XRD and thermogravimetric analysis and DFT calculations enabled estimation of the energies of the Br⋅⋅⋅Br contacts (1.1–4.6 kcal mol −1 ).
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