z-logo
Premium
Pentafluoroethylated Compounds of Silicon, Germanium and Tin
Author(s) -
Wiesemann Markus,
Hoge Berthold
Publication year - 2018
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201801292
Subject(s) - tin , germanium , hypervalent molecule , carbon group , main group element , reagent , chemistry , silicon , halide , trifluoromethyl , molecule , inorganic chemistry , group (periodic table) , organic chemistry , transition metal , alkyl , catalysis
In this contribution we present an account on pentafluoroethylated compounds of silicon, germanium and tin. The pronounced electron‐withdrawing effect of the pentafluoroethyl group leads to a markedly increased Lewis acidity at the central atom which results in the stabilization of hypervalent complexes, anionic element(II) species as well as remarkable reactivities of element‐element and element‐hydrogen bonds. By addition to unsaturated C−C bonds or by reaction with organic halides as well as transition‐metal complexes the molecules bearing a pentafluoroethyl‐element group are readily accessible. Moreover, the utilization of pentafluoroethyl groups facilitates the formation of donor‐stabilized germylenes and stannylenes. A series of such compounds serves as suitable pentafluoroethylation reagents. Conversely to the well‐studied trifluoromethyl derivatives these compounds frequently exhibit a higher thermostability, which allows a more convenient handling.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here