Enantioselective Synthesis of Fully Benzenoid Single and Double Carbohelicenes via Gold‐Catalyzed Intramolecular Hydroarylation | Zendy

Satoh Masakazu | Zendy; Shibata Yu | Zendy; Tanaka Ken | Zendy

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Enantioselective Synthesis of Fully Benzenoid Single and Double Carbohelicenes via Gold‐Catalyzed Intramolecular Hydroarylation

Author(s) -

Satoh Masakazu,

Shibata Yu,

Tanaka Ken

Publication year - 2018

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201800986

Subject(s) - enantioselective synthesis , intramolecular force , catalysis , combinatorial chemistry , chemistry , stereochemistry , organic chemistry

The enantioselective synthesis of fully benzenoid single and double carbo[6]helicenes has been achieved via the gold‐catalyzed intramolecular hydroarylation. The single crystal of the racemic double carbo[6]helicene consists of unique layer structures like timbers with halving joints in the woodworking. Furthermore, the double carbo[6]helicenes exhibited relatively large CPL activities among chiral small organic molecules.

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