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Towards Useful Boronates through Atom‐Economical Catalyzed Cascade Reactions
Author(s) -
Buñuel Elena,
Cárdenas Diego J.
Publication year - 2018
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201800659
Subject(s) - catalysis , metathesis , cascade , chemistry , salt metathesis reaction , atom (system on chip) , combinatorial chemistry , atom economy , transition metal , metal , organic chemistry , computer science , parallel computing , chromatography , polymerization , polymer
Metal‐catalyzed borylative cyclization reactions of polyunsaturated compounds allow concomitant formation of C−C and C−B bonds to provide cyclic boronates, which constitute synthetically useful intermediates. Recent developments using first‐row transition metals as catalysts provide fully atom‐economical reactions that follow mechanisms involving σ‐bond metathesis.