Towards Useful Boronates through Atom‐Economical Catalyzed Cascade Reactions | Zendy

Buñuel Elena | Zendy; Cárdenas Diego J. | Zendy

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Towards Useful Boronates through Atom‐Economical Catalyzed Cascade Reactions

Author(s) -

Buñuel Elena,

Cárdenas Diego J.

Publication year - 2018

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201800659

Subject(s) - catalysis , metathesis , cascade , chemistry , salt metathesis reaction , atom (system on chip) , combinatorial chemistry , atom economy , transition metal , metal , organic chemistry , computer science , parallel computing , chromatography , polymerization , polymer

Metal‐catalyzed borylative cyclization reactions of polyunsaturated compounds allow concomitant formation of C−C and C−B bonds to provide cyclic boronates, which constitute synthetically useful intermediates. Recent developments using first‐row transition metals as catalysts provide fully atom‐economical reactions that follow mechanisms involving σ‐bond metathesis.

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