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Synthesis of Fluidized CO 2 Sorbents Based on Diamine Coordinated to Metal–Organic Frameworks by Direct Conversion of Metal Oxides Supported on Mesoporous Silica
Author(s) -
Luz Ignacio,
Soukri Mustapha,
Lail Marty
Publication year - 2018
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201800612
Subject(s) - materials science , fluidized bed , mesoporous material , flue gas , metal organic framework , chemical engineering , combustion , metal , catalysis , adsorption , metallurgy , organic chemistry , chemistry , engineering
A general and efficient method for shaping MOFs into fluidized forms has been developed by direct conversion of metal oxides supported on fluidized mesoporous silica. The resulting fluidized MOF hybrid materials containing diamines coordinated at the open metal sites have been studied as CO 2 solid sorbents from post‐combustion flue gas showing similar performance than their bulk counterparts. These new fluidized MOF hybrid materials can be used for other applications involving fluidized bed reactor configurations, in which MOFs have never been considered.