Enhanced Li Storage Stability Induced by Locating Sn in Metal–Organic Frameworks | Zendy

Wu Na | Zendy; Wang Wei | Zendy; Kou LuQing | Zendy; Zhang Xue | Zendy; Shi YaRu | Zendy; Li TaoHai | Zendy; Li Feng | Zendy; Zhou JingMing | Zendy; Wei Yu | Zendy

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Enhanced Li Storage Stability Induced by Locating Sn in Metal–Organic Frameworks

Author(s) -

Wu Na,

Wang Wei,

Kou LuQing,

Zhang Xue,

Shi YaRu,

Li TaoHai,

Li Feng,

Zhou JingMing,

Wei Yu

Publication year - 2018

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201800215

Subject(s) - anode , lithium (medication) , materials science , metal , metal organic framework , cycling , cracking , chemical engineering , metallurgy , composite material , electrode , chemistry , adsorption , organic chemistry , medicine , archaeology , engineering , history , endocrinology

By locating elemental Sn in an open anionic framework, the particle cracking arising from huge volume expansion of Sn‐based anode materials during lithiation/delithiation is alleviated, and the cycling stability is greatly improved. The Sn‐based metal–organic framework anode material shows superior cyclic stability, with a capacity retention >92 % (after 200 cycles) and high lithium storage capacity (610 mAh g −1 ).

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