Complexes of Stiboranium Mono‐, Di‐, and Trications | Zendy

Frazee Christopher | Zendy; Burford Neil | Zendy; McDonald Robert | Zendy; Ferguson Michael J. | Zendy; Decken Andreas | Zendy; Patrick Brian O. | Zendy

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Complexes of Stiboranium Mono‐, Di‐, and Trications

Author(s) -

Frazee Christopher,

Burford Neil,

McDonald Robert,

Ferguson Michael J.,

Decken Andreas,

Patrick Brian O.

Publication year - 2018

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201800196

Subject(s) - pnictogen , chlorobenzene , chemistry , redox , medicinal chemistry , reductive elimination , oxide , stereochemistry , inorganic chemistry , catalysis , organic chemistry , physics , superconductivity , quantum mechanics

Reaction of Ph 2 SbCl 3 with 2,2′‐bipyridine and Me 3 SiOSO 2 CF 3 releases chlorobenzene, which is interpreted as a reductive (Sb V /Sb III ) elimination from a complex of a stiboranium cation. Conversely, reactions of Ph 2 SbCl 3 with 4‐methylpyridine‐ N ‐oxide and AgOSO 2 CF 3 give redox‐resistant complexes with the generic formulae [Ph 2 SbCl 3−x L x+1 ][OTf] x , including a compound containing a pnictogen(V) trication.

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