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Frontispiece: Isovalent Ag III /Ag III , Ag II /Ag II , Mixed‐Valent Ag II /Ag III , and Corrolato‐Based Mixed‐Valency in β,β′‐Linked [Bis{corrolato‐silver}] n Complexes
Author(s) -
Patra Bratati,
Sobottka Sebastian,
Sinha Woormileela,
Sarkar Biprajit,
Kar Sanjib
Publication year - 2017
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201785663
Subject(s) - valency , electron paramagnetic resonance , context (archaeology) , crystallography , chemistry , materials science , photochemistry , physics , nuclear magnetic resonance , geology , philosophy , linguistics , paleontology
The power of the combination of electrochemistry, UV/Vis/NIR/EPR spectroelectrochemistry and DFT calculations for mapping the electronic structures of unusual disilver and dicorrole containing mixed‐valent compounds united in a surprisingly flexible structure is depicted in the artwork. The joining of the two corrole units to achieve this feat and the importance of the physical and theoretical methods are put into the larger context of the world. For more information see the Communication by B. Sarkar, S. Kar et al. on page 13858 ff.