Frontispiece: A Consecutive C−H Functionalization Triggered by Oxidation of Active sp 3  C−H Bonds: Construction of 3,4‐Dihydroquinoline‐3‐one Derivatives | Zendy

Jia Xiaodong | Zendy; Hou Wentao | Zendy; Shao Yu | Zendy; Yuan Yu | Zendy; Chen Qian | Zendy; Li Pengfei | Zendy; Liu Xiaofei | Zendy; Ji Honghe | Zendy

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Frontispiece: A Consecutive C−H Functionalization Triggered by Oxidation of Active sp 3 C−H Bonds: Construction of 3,4‐Dihydroquinoline‐3‐one Derivatives

Author(s) -

Jia Xiaodong,

Hou Wentao,

Shao Yu,

Yuan Yu,

Chen Qian,

Li Pengfei,

Liu Xiaofei,

Ji Honghe

Publication year - 2017

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Reports

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201785363

Subject(s) - surface modification , inert , chemistry , ring (chemistry) , medicinal chemistry , carbon fibers , stereochemistry , organic chemistry , materials science , composite number , composite material

Construction of 3,4‐dihydroquinoline‐3‐ones is achieved by radical cation‐initiated aerobic oxidation. In this transformation, the active sp 3 C−H bonds of glycines act as the “Achilles′ heel”, triggering the consecutive oxidation of the inert C−H bonds. Furthermore, one heterocylic ring with a quaternary carbon center is also constructed. More information can be found in the Communication by X. Jia et al. on page 12980 ff.

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