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Frontispiece: A Consecutive C−H Functionalization Triggered by Oxidation of Active sp 3 C−H Bonds: Construction of 3,4‐Dihydroquinoline‐3‐one Derivatives
Author(s) -
Jia Xiaodong,
Hou Wentao,
Shao Yu,
Yuan Yu,
Chen Qian,
Li Pengfei,
Liu Xiaofei,
Ji Honghe
Publication year - 2017
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201785363
Subject(s) - surface modification , inert , chemistry , ring (chemistry) , medicinal chemistry , carbon fibers , stereochemistry , organic chemistry , materials science , composite number , composite material
Construction of 3,4‐dihydroquinoline‐3‐ones is achieved by radical cation‐initiated aerobic oxidation. In this transformation, the active sp 3 C−H bonds of glycines act as the “Achilles′ heel”, triggering the consecutive oxidation of the inert C−H bonds. Furthermore, one heterocylic ring with a quaternary carbon center is also constructed. More information can be found in the Communication by X. Jia et al. on page 12980 ff.

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