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Frontispiece: Harnessing White‐Light Luminescence via Tunable Singlet‐and Triplet‐Derived Emissions Based on Gold(III) Complexes *
Author(s) -
Bachmann Michael,
Blacque Olivier,
Venkatesan Koushik
Publication year - 2017
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201784062
Subject(s) - intersystem crossing , phosphorescence , chromaticity , luminescence , photochemistry , singlet state , fluorescence , white light , energy transfer , materials science , excitation , optoelectronics , chemistry , optics , physics , molecular physics , atomic physics , excited state , quantum mechanics
Rainbow from gold : A single‐component white‐light emitters based on gold(III) complexes with tailored ligand scaffolds through a rational design approach was synthesized. An exquisite control of the ratio between fluorescence and phosphorescence was varied via excitation energy due to hyper‐intersystem‐crossing to fine tune the chromaticity of the white‐light emission with excellent CIE coordinates both in solution and thin films. For more information, see the Communication by K. Venkatesan et al. on page 9451 ff.