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Frontispiece: β 2, 2 ‐Amino Acid N ‐Carboxyanhydrides Relying on Sequential Enantioselective C(4)‐Functionalization of Pyrrolidin‐2,3‐diones and Regioselective Baeyer–Villiger Oxidation
Author(s) -
Badiola Eider,
Olaizola Iurre,
Vázquez Ana,
Vera Silvia,
Mielgo Antonia,
Palomo Claudio
Publication year - 2017
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201783464
Subject(s) - regioselectivity , enantioselective synthesis , chemistry , surface modification , adduct , organocatalysis , stereochemistry , combinatorial chemistry , catalysis , organic chemistry
Expanding the field : A simple metal free machinery comprised by an organocatalytic Michael reaction of pyrrolidin‐2,3‐diones and a regioselective Baeyer–Villiger rearrangement of the resultant adducts is reported en route to β 2,2 ‐amino acid coupled products. For more details, see the Full Paper by C. Palomo et al. on page 8185 ff.