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Frontispiece: Dinuclear Iron(III) and Nickel(II) Complexes Containing N‐( 2‐Pyridylmethyl)‐ N ′‐(2‐hydroxyethyl)ethylenediamine: Catalytic Oxidation and Magnetic Properties
Author(s) -
Jeong Ah Rim,
Shin Jong Won,
Jeong Jong Hwa,
Bok Kwon Hee,
Kim Cheal,
Jeong Donghyun,
Cho Jaeheung,
Hayami Shinya,
Min Kil Sik
Publication year - 2017
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201781363
Subject(s) - catalysis , ethylenediamine , antiferromagnetism , nickel , chemistry , olefin fiber , transition metal , polymer chemistry , crystallography , ferromagnetism , metal , ligand (biochemistry) , medicinal chemistry , stereochemistry , inorganic chemistry , organic chemistry , physics , quantum mechanics , condensed matter physics , biochemistry , receptor
Coordination Complexes Transition‐metal binuclear complexes with tetradentate ligands are very useful in applications for catalytic reactions and molecular magnetic materials. Two azido‐bridged Ni(II) complex shows strong ferromagnetic coupling via the bridged end‐on azido ligands, while two ethoxo‐bridged Fe(III) complex exhibits antiferromagnetic interaction via the bridged ethoxo groups. Remarkably, the Ni(II) binuclear complex shows excellent catalytic activities for the epoxidation of aliphatic, aromatic, and terminal olefins, in which it is the first example as an efficient Ni(II) catalyst for the terminal olefin epoxidation. More information can be found in the Full Paper by K. S. Min et al. on page 3023 ff.