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Frontispiece: Transition‐Metal‐Catalyzed Electrophilic Amination: Application of O ‐Benzoylhydroxylamines in the Construction of the C−N Bond
Author(s) -
Dong Xu,
Liu Qing,
Dong Yunhui,
Liu Hui
Publication year - 2017
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201781161
Subject(s) - amination , transition metal , electrophile , electrophilic amination , catalysis , bond , chemistry , combinatorial chemistry , stereochemistry , medicinal chemistry , organic chemistry , business , finance
Electrophilic Amination The task of realizing selective assembly of amines from readily available precursors has become a prominent objective in organic chemistry. The importance of C−N bond construction by application of O ‐benzoylhydroxylamines in transition‐metal‐catalyzed electrophilic amination has led to the rapid development of this field. In their Review article on page 2481 ff., Q. Liu, H. Liu and colleagues describe the recent advances of O ‐benzoylhydroxylamines involved in electrophilic amination catalyzed by transition metals. Several pioneering studies and some of the relevant mechanisms are discussed.