Ruthenium‐Catalyzed Selective C−C Coupling of Allylic Alcohols with Free Indoles: Influence of the Metal Catalyst | Zendy

Xia YingQi | Zendy; Li Chao | Zendy; Liu Man | Zendy; Dong Lin | Zendy

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Ruthenium‐Catalyzed Selective C−C Coupling of Allylic Alcohols with Free Indoles: Influence of the Metal Catalyst

Author(s) -

Xia YingQi,

Li Chao,

Liu Man,

Dong Lin

Publication year - 2018

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201706080

Subject(s) - catalysis , ruthenium , allylic rearrangement , chemistry , ketone , surface modification , metal , medicinal chemistry , alkylation , coupling reaction , organic chemistry , cascade , combinatorial chemistry , chromatography

Versatile reactive activities of allyl alcohols with free indoles in C−H functionalization reactions were investigated. Direct alkylation or cascade cyclization reactions could be selectively controlled based on the catalyst system: Ru(PPh 3 ) 3 Cl 2 provided C3‐substituted β‐ketone indoles whereas [Ru( p ‐cymene)Cl 2 ] 2 yielded cyclized indoles.

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