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2D and 3D Coordination Networks of Polynuclear Bismuth Oxido/Hydroxido Sulfonato Clusters from Low Temperature Solid‐State Metathesis Reactions
Author(s) -
Senevirathna Dimuthu C.,
Werrett Melissa V.,
Blair Victoria L.,
Mehring Michael,
Andrews Philip C.
Publication year - 2018
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201705981
Subject(s) - bismuth , chemistry , metathesis , benzene , salt metathesis reaction , medicinal chemistry , potassium , solid state , stereochemistry , polymerization , organic chemistry , polymer
Solid‐state metathesis (SSM) reactions between Bi(NO 3 ) 3 ⋅5 H 2 O and potassium benzene‐1,2‐disulfonate (=1,2‐BDS K 2 ), sodium benzene‐1,3‐disulfonate (=1,3‐BDS Na 2 ) allows access to the first 2D, {[Bi 6 O 4 (OH) 4 (1–2BDS) 2 (NO 3 ) 2 ⋅4 H 2 O]⋅11 H 2 O} ∞ and {[Bi 22 O 24 (OH) 6 (1,3‐BDS) 6 ⋅12 DMSO]⋅3 DMSO⋅4 H 2 O} ∞ , and 3D, {[Bi 6 O 4 (OH) 4 (1,3‐BDS) 3 ⋅4 H 2 O]⋅6 H 2 O} ∞ , polymeric networks of sulfonato encapsulated polynuclear bismuth oxido/hydroxido clusters.