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Cover Feature: An Amino‐Functionalized Metal‐Organic Framework, Based on a Rare Ba 12 (COO) 18 (NO 3 ) 2 Cluster, for Efficient C 3 /C 2 /C 1 Separation and Preferential Catalytic Performance (Chem. Eur. J. 9/2018)
Author(s) -
Fan Weidong,
Wang Yutong,
Zhang Qian,
Kirchon Angelo,
Xiao Zhenyu,
Zhang Liangliang,
Dai Fangna,
Wang Rongming,
Sun Daofeng
Publication year - 2018
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201705801
Subject(s) - microporous material , selectivity , adsorption , metal organic framework , cover (algebra) , cluster (spacecraft) , porosity , materials science , gossip , metal , chemistry , chemical engineering , computer science , organic chemistry , mechanical engineering , social psychology , engineering , catalysis , programming language , psychology
An amino‐functionalized and Ba 12 (COO) 18 (NO 3 ) 2 ‐based microporous metal−organic framework (UPC‐33) has been synthesized. UPC‐33 displays not only permanent porosity, but also high adsorption heat of CO 2 and selectivity of CO 2 /CH 4. In addition, UPC‐33 exerts a high separation selectivity for C 3 light hydrocarbons relative to CH 4 , and can selectively adsorb C 3 H 6 from C 2 hydrocarbons. Based on the above work, the cover depicts a traditional Chinese‐style gossip image of UPC‐33, which acts as a platform for adsorbing C 3 while separating C 1 . More information can be found in the Full Paper by L. Zhang, D. Sun et al. on page 2137.