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Phosphine/Sulfoxide‐Supported Carbon(0) Complex
Author(s) -
Lozano González Mariana,
Bousquet Laura,
Hameury Sophie,
Alvarez Toledano Cecilio,
SaffonMerceron Nathalie,
Branchadell Vicenç,
Maerten Eddy,
Baceiredo Antoine
Publication year - 2018
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201705557
Subject(s) - phosphine , sulfoxide , sulfide , chemistry , carbon fibers , organic chemistry , materials science , catalysis , composite number , composite material
A new carbon(0) complex 2 with two different L ligands, a phosphine and a sulfoxide, was synthesized and fully characterized. This new type of carbone exhibits excellent coordination ability, in contrast to the related phosphine/sulfide‐supported carbon(0) complexes. Several organometallic complexes were isolated and, of special interest, the ν av (CO) value of Rh I ‐dicarbonyl complex indicates that 2 has a donor capability superior to classical NHCs.