Phosphine/Sulfoxide‐Supported Carbon(0) Complex | Zendy

Lozano González Mariana | Zendy; Bousquet Laura | Zendy; Hameury Sophie | Zendy; Alvarez Toledano Cecilio | Zendy; SaffonMerceron Nathalie | Zendy; Branchadell Vicenç | Zendy; Maerten Eddy | Zendy; Baceiredo Antoine | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Phosphine/Sulfoxide‐Supported Carbon(0) Complex

Author(s) -

Lozano González Mariana,

Bousquet Laura,

Hameury Sophie,

Alvarez Toledano Cecilio,

SaffonMerceron Nathalie,

Branchadell Vicenç,

Maerten Eddy,

Baceiredo Antoine

Publication year - 2018

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201705557

Subject(s) - phosphine , sulfoxide , sulfide , chemistry , carbon fibers , organic chemistry , materials science , catalysis , composite number , composite material

A new carbon(0) complex 2 with two different L ligands, a phosphine and a sulfoxide, was synthesized and fully characterized. This new type of carbone exhibits excellent coordination ability, in contrast to the related phosphine/sulfide‐supported carbon(0) complexes. Several organometallic complexes were isolated and, of special interest, the ν av (CO) value of Rh I ‐dicarbonyl complex indicates that 2 has a donor capability superior to classical NHCs.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research