Cover Feature: One‐Step Assembly of Visible and Near‐Infrared Emitting Metallacrown Dimers Using a Bifunctional Linker (Chem. Eur. J. 5/2018) | Zendy

Nguyen Tu N. | Zendy; Chow Chun Y. | Zendy; Eliseeva Svetlana V. | Zendy; Trivedi Evan R. | Zendy; Kampf Jeff W. | Zendy; Martinić Ivana | Zendy; Petoud Stéphane | Zendy; Pecoraro Vincent L. | Zendy

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Cover Feature: One‐Step Assembly of Visible and Near‐Infrared Emitting Metallacrown Dimers Using a Bifunctional Linker (Chem. Eur. J. 5/2018)

Author(s) -

Nguyen Tu N.,

Chow Chun Y.,

Eliseeva Svetlana V.,

Trivedi Evan R.,

Kampf Jeff W.,

Martinić Ivana,

Petoud Stéphane,

Pecoraro Vincent L.

Publication year - 2018

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201705225

Subject(s) - bifunctional , linker , cover (algebra) , carboxylate , ion , solid state , chemistry , infrared , surface modification , luminescence , crystallography , feature (linguistics) , materials science , stereochemistry , optoelectronics , organic chemistry , computer science , physics , mechanical engineering , linguistics , philosophy , optics , engineering , catalysis , operating system

Ga III /Ln III metallacrown (MC) complexes with a dimeric structure have been designed, synthesized and characterized. The presence of the bridge in the [LnGa 4 ] 2 allows for a broad variety of functionalization with chemical groups of different nature through carboxylate substitution. Moreover, the MC scaffold in [LnGa 4 ] 2 is able to efficiently sensitize the characteristic emission of Nd, Pr, Sm, Tb, Dy, Ho, Er and Yb ions in the visible and/or NIR ranges in the solid state. More information can be found in the Communication by S. V. Eliseeva, S. Petoud, V. L Pecoraro et al. on page 1031.

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