Mononuclear Alkali Metal Organoperoxides Stabilized by an NNNN‐Macrocycle and Short Hydrogen Bonds from ROOH Molecules | Zendy

Osseili Hassan | Zendy; Truong KhaiNghi | Zendy; Spaniol Thomas P. | Zendy; Mukherjee Debabrata | Zendy; Englert Ulli | Zendy; Okuda Jun | Zendy

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Mononuclear Alkali Metal Organoperoxides Stabilized by an NNNN‐Macrocycle and Short Hydrogen Bonds from ROOH Molecules

Author(s) -

Osseili Hassan,

Truong KhaiNghi,

Spaniol Thomas P.,

Mukherjee Debabrata,

Englert Ulli,

Okuda Jun

Publication year - 2017

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201704758

Subject(s) - alkali metal , derivative (finance) , molecule , hydrogen bond , chemistry , metal , stereochemistry , medicinal chemistry , crystallography , organic chemistry , financial economics , economics

A series of light alkali metal organoperoxides [MOOR] (M=Li, Na, K; R= t Bu, CMe 2 Ph) were isolated in mononuclear form, aided by the tetradentate and neutral NNNN‐type macrocycle Me 4 TACD (L; Me 4 [12]aneN 4 =1,4,7,10‐tetramethyl‐1,4,7,10‐tetraazacyclododecane) and strong hydrogen bonds from additional ROOH molecules. The Na and K compounds are characterized by short O−H⋅⋅⋅O contacts, in the case of the Na derivative as short as 2.41 Å.

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