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Front Cover: Di(hydroperoxy)alkane Adducts of Phosphine Oxides: Safe, Solid, Stoichiometric, and Soluble Oxidizing Agents (Chem. Eur. J. 67/2017)
Author(s) -
Ahn Shin Hye,
Bhuvanesh Nattamai,
Blümel Janet
Publication year - 2017
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201704702
Subject(s) - oxidizing agent , adduct , phosphine , alkane , stoichiometry , chemistry , characterization (materials science) , polymer chemistry , combinatorial chemistry , materials science , organic chemistry , catalysis , nanotechnology
The most fascinating feature of novel di(hydroperoxy)alkane adducts of phosphine oxides R 3 PO⋅(HOO) 2 CR′R“ is that for all substituents R, R′, and R” large single crystals are easily obtained, enabling easy purification and characterization. There are several other advantages, including facile synthesis at ambient temperature, they can be stored on a shelf indefinitely without loss of oxidizing power, and are soluble in organic solvents. More information can be found in the Full Paper by J. Blümel et al. on page 16998.