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An {As 4 Cu 4 [Cu(H 2 O)] 12 } Cluster Incorporated within Four [Nb 7 O 22 ] 9− Units
Author(s) -
Li Li,
Dong Kaili,
Ma Pengtao,
Zhang Chao,
Niu Jingyang,
Wang Jingping
Publication year - 2017
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201704071
Subject(s) - cluster (spacecraft) , copper , crystallography , chemistry , materials science , analytical chemistry (journal) , metallurgy , computer science , operating system , chromatography
A gigantic 16‐copper‐containing 28‐niobate cluster, Na 14 K 7 H 5 {As 4 Cu 4 [Cu(H 2 O)] 12 Nb 28 O 109 }⋅37.5 H 2 O ( 1 ), has been prepared by a one‐pot reaction, which is the first example of arsenic copper clusters containing polyoxoniobate, and the first tetrahedral arrangement of both the Cu cluster and the [Nb 7 O 22 ] 9− subunits.
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