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Pd/C‐Catalyzed Aminocarbonylation of Aryl Iodides with Anthranils in Water Using Mo(CO) 6 as the CO Source
Author(s) -
Wang Zechao,
Yin Zhiping,
Wu XiaoFeng
Publication year - 2017
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201703994
Subject(s) - catalysis , aryl , inert gas , inert , solvent , chemistry , combinatorial chemistry , atmosphere (unit) , organic chemistry , alkyl , physics , thermodynamics
A convenient procedure for the synthesis of N‐ (2‐carbonylaryl)benzamides has been developed. Through Pd/C‐catalyzed aminocarbonylation of anthranils with various hindered and functionalized aryl iodides, the desired amides were afforded in moderate to good yields. The protocol is advantageous due to the recyclable Pd/C catalyst, safe Mo(CO) 6 as the solid CO source, and environmentally benign water as solvent. No inert atmosphere protection is needed.