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Heterometallic Zn 3 Ln 3 Ensembles Containing (μ 6 ‐CO 3 ) Ligand and Triangular Disposition of Ln 3+ ions: Analysis of Single‐Molecule Toroic (SMT) and Single‐Molecule Magnet (SMM) Behavior
Author(s) -
Goura Joydeb,
Colacio Enrique,
Herrera Juan Manuel,
Suturina Elizaveta A.,
Kuprov Ilya,
Lan Yanhua,
Wernsdorfer Wolfgang,
Chandrasekhar Vadapalli
Publication year - 2017
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201703842
Subject(s) - ground state , magnetization , chemistry , ion , ligand (biochemistry) , excited state , relaxation (psychology) , atomic physics , magnetic moment , molecule , crystallography , molecular physics , magnetic field , physics , condensed matter physics , quantum mechanics , psychology , social psychology , biochemistry , receptor , organic chemistry
Two new heterometallic Zn 3 Ln 3 (Ln 3+ =Dy, Tb) complexes, with a double triangular topology of the metal ions, have been assembled from the polytopic Mannich base ligand 6,6′‐{[2‐(dimethylamino)ethylazanediyl]bis(methylene)}bis(2‐methoxy‐4‐methylphenol) (H 2 L) with the aid of an in situ generated carbonate ligand from atmospheric CO 2 fixation. Theoretical calculations indicate axial ground states for the Ln 3+ ions in these complexes, with their local magnetic moments being almost coplanar and tangential to the Ln 3+ atoms that define the equilateral triangle. Therefore, they can be considered as single‐molecule toroics (SMTs) with almost zero total magnetic moment. Micro‐SQUID measurements on the Dy 3+ counterpart show hysteresis loops below 3 K that have an S‐shape, with large coercive fields opening upon cooling. This behavior is typical of a single molecule magnet (SMM) with very slow zero‐field relaxation. At around ±0.35 T, the loops have a broad step, which is due to a direct relaxation process and corresponds to an acceleration of the relaxation of the magnetization, also observed at this magnetic field from ac susceptibility measurements. Simulations suggest that the broad step corresponds to two level avoidance of crossing points where the spin chiral Kramers doublet meets excited states of the coupled manifold, whose position is defined by exchange and dipole interactions. The Tb 3+ counterpart does not exhibit SMM behavior, which is due to the fact that the degeneracy of the ground state of the exchange coupled system is lifted at zero field, thus favoring quantum tunneling of magnetization (QTM).