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Metal‐Based Diversity for Crystalline Metal‐Fullerene Frameworks
Author(s) -
Kraft Andreas,
Roger Chantal,
Schmidt David,
Stangl Johannes,
MüllerBuschbaum Klaus,
Beuerle Florian
Publication year - 2017
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201703709
Subject(s) - fullerene , sorption , metal , materials science , porosity , polymerization , metal organic framework , diffraction , metal ions in aqueous solution , crystallography , alkyl , chemical engineering , chemistry , organic chemistry , polymer , metallurgy , composite material , optics , adsorption , physics , engineering
Four different three‐dimensional metal–fullerene frameworks were synthesized through polymerization of two C 60 ‐derived dodecaacids with varying alkyl spacers in the presence of Ca 2+ , Cu 2+ or Cd 2+ ions. Structural analysis of the frameworks was performed by single‐crystal X‐ray diffraction and porosity of the materials was investigated by sorption measurements.