Mild Decarboxylative C−H Alkylation: Computational Insights for Solvent‐Robust Ruthenium(II) Domino Manifold | Zendy

Kumar N. Y. Phani | Zendy; Rogge Torben | Zendy; Yetra Santhivardhana Reddy | Zendy; Bechtoldt Alexander | Zendy; Clot Eric | Zendy; Ackermann Lutz | Zendy

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Mild Decarboxylative C−H Alkylation: Computational Insights for Solvent‐Robust Ruthenium(II) Domino Manifold

Author(s) -

Kumar N. Y. Phani,

Rogge Torben,

Yetra Santhivardhana Reddy,

Bechtoldt Alexander,

Clot Eric,

Ackermann Lutz

Publication year - 2017

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201703680

Subject(s) - ruthenium , decarboxylation , domino , chemistry , catalysis , solvent , alkylation , combinatorial chemistry , organic chemistry

Computational studies on decarboxylative C−H alkenylations provided key insights into the solvent‐robust nature of C−H activation/decarboxylation domino reactions. These properties were exploited for ruthenium(II)‐catalyzed C−H alkylations by a decarboxylative process with ample scope under copper‐free and silver‐free reaction conditions.

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