Premium
Cover Feature: Synthesis of gem ‐Dinitromethylated and Fluorodinitromethylated Derivatives of 5,5′‐Dinitro‐bis‐1,2,4‐triazole as Promising High‐Energy‐Density Materials (Chem. Eur. J. 52/2017)
Author(s) -
Huang Shi,
Tian Junjun,
Qi Xiujuan,
Wang Kangcai,
Zhang Qinghua
Publication year - 2017
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201703132
Subject(s) - cover (algebra) , detonation , combinatorial chemistry , 1,2,4 triazole , thermal stability , feature (linguistics) , sensitivity (control systems) , chemistry , triazole , materials science , organic chemistry , explosive material , engineering , mechanical engineering , linguistics , philosophy , electronic engineering
A new family of gem ‐dinitromethylated and fluorodinitromethylated energetic compounds based on 5,5’‐dinitro‐3,3’‐bis‐1,2,4‐triazole (DNBT) shows high energy density, good thermal stability, and excellent detonation properties. The proposed strategy of introducing gem ‐dinitromethyl and fluorodinitromethyl groups into DNBT frameworks demonstrates a great promise for developing new‐generation high‐energy‐density materials (HEDMs) with high‐performing detonation level and low sensitivity. More information can be found in the Full Paper by Q. Zhang et al. on page 12787.