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Back Cover: Design, Synthesis, and Chemistry of Bis(σ)borate and Agostic Complexes of Group 7 Metals (Chem. Eur. J. 41/2017)
Author(s) -
Saha Koushik,
Ramalakshmi Rongala,
Gomosta Suman,
Pathak Kriti,
Dorcet Vincent,
Roisnel Thierry,
Halet JeanFrançois,
Ghosh Sundargopal
Publication year - 2017
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201702439
Subject(s) - chemistry , boron , manganese , agostic interaction , phosphine , lability , ligand (biochemistry) , amine gas treating , metal , main group element , medicinal chemistry , stereochemistry , crystallography , polymer chemistry , transition metal , organic chemistry , catalysis , biochemistry , receptor
The lability of the CO ligands of manganese bis(σ)borate complex, [Mn(CO) 3 (μ‐H) 2 HB(NCSC 6 H 4 )NR] (R=NCSC 6 H 4 ) was studied with different phosphine ligands. Treatment of this Mn‐bis(σ)borate complex with PPh 3 led to the formation of two manganese bis(σ)borate complexes, [(PPh 3 )(CO) 2 Mn(μ‐H) 2 HB(NCSC 6 H 4 )NR] and [(PPh 3 )(CO) 2 Mn(μ‐H) 2 HBNR(NCSC 6 H 4 )] (R=NCSC 6 H 4 ), as structural isomers having two different arrangements of the bis(benzothiazol‐2‐yl)amine ligand around the central metal atom. More information can be found in the Full Paper by S. Ghosh et al. on page 9812.