Premium
Topotactic Synthesis of Porous Cobalt Ferrite Platelets from a Layered Double Hydroxide Precursor and Their Application in Oxidation Catalysis
Author(s) -
Ortega Klaus Friedel,
Anke Sven,
Salamon Soma,
Özcan Fatih,
Heese Justus,
Andronescu Corina,
Landers Joachim,
Wende Heiko,
Schuhmann Wolfgang,
Muhler Martin,
Lunkenbein Thomas,
Behrens Malte
Publication year - 2017
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201702248
Subject(s) - spinel , cobalt , catalysis , calcination , hydroxide , crystallization , inorganic chemistry , materials science , ferrite (magnet) , dehydrogenation , chemical engineering , chemistry , metallurgy , organic chemistry , engineering , composite material
Monocrystalline, yet porous mosaic platelets of cobalt ferrite, CoFe 2 O 4 , can be synthesized from a layered double hydroxide (LDH) precursor by thermal decomposition. Using an equimolar mixture of Fe 2+ , Co 2+ , and Fe 3+ during co‐precipitation, a mixture of LDH, (Fe II Co II ) 2/3 Fe III 1/3 (OH) 2 (CO 3 ) 1/6 ⋅ m H 2 O, and the target spinel CoFe 2 O 4 can be obtained in the precursor. During calcination, the remaining Fe II fraction of the LDH is oxidized to Fe III leading to an overall Co 2+ :Fe 3+ ratio of 1:2 as required for spinel crystallization. This pre‐adjustment of the spinel composition in the LDH precursor suggests a topotactic crystallization of cobalt ferrite and yields phase pure spinel in unusual anisotropic platelet morphology. The preferred topotactic relationship in most particles is [111] Spinel ∥[001] LDH . Due to the anion decomposition, holes are formed throughout the quasi monocrystalline platelets. This synthesis approach can be used for different ferrites and the unique microstructure leads to unusual chemical properties as shown by the application of the ex‐LDH cobalt ferrite as catalyst in the selective oxidation of 2‐propanol. Compared to commercial cobalt ferrite, which mainly catalyzes the oxidative dehydrogenation to acetone, the main reaction over the novel ex‐LDH cobalt is dehydration to propene. Moreover, the oxygen evolution reaction (OER) activity of the ex‐LDH catalyst was markedly higher compared to the commercial material.