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A Novel Open‐Framework Copper Borovanadate with Enhanced Catalytic Performance for Oxidation of Benzylic C−H Bond
Author(s) -
Feng Yuquan,
Zhong Zhiguo,
Wang Hongwei,
Fan Huitao,
Bi Dongqin,
Wang Lu,
Xing Zhengzheng,
Qiu Dongfang
Publication year - 2017
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201702207
Subject(s) - copper , catalysis , linkage (software) , ion , ring (chemistry) , chemistry , crystallography , polymer chemistry , stereochemistry , materials science , combinatorial chemistry , medicinal chemistry , organic chemistry , biochemistry , gene
A novel open‐framework copper borovanadate, with a 6‐connected topological net and 1D 8‐membered ring channels, has been obtained for the first time. The compound not only exhibits a unique ‐B 3 O 7 (OH)‐Cu‐B(OH) 3 linkage and features the largest ratio between TM 2+ (Cu 2+ ) and the borovanadate anion, but also possesses enhanced catalytic performance, high recyclability, and stability during the oxidation of benzylic C−H bonds.