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Vanadium Hydroxide Cluster Ions in the Gas Phase: Bond‐Forming Reactions of Doubly‐Charged Negative Ions by SO 2 ‐Promoted V−O Activation
Author(s) -
Troiani Anna,
Rosi Marzio,
Garzoli Stefania,
Salvitti Chiara,
de Petris Giulia
Publication year - 2017
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201702165
Subject(s) - hydroxide , reactivity (psychology) , vanadium , ion , chemistry , cluster (spacecraft) , sulfur , gas phase , inorganic chemistry , phase (matter) , organic chemistry , medicine , alternative medicine , pathology , computer science , programming language
The gas‐phase reactivity of doubly‐charged vanadium hydroxides anions with SO 2 has been studied by experimental and computational methods. The obtained results highlight the role of sulfur dioxide in promoting unprecedented bond‐forming reactions, which produce singly‐charged products by breaking the V x O y skeleton or a terminal V−O bond.