Vanadium Hydroxide Cluster Ions in the Gas Phase: Bond‐Forming Reactions of Doubly‐Charged Negative Ions by SO 2 ‐Promoted V−O Activation | Zendy

Troiani Anna | Zendy; Rosi Marzio | Zendy; Garzoli Stefania | Zendy; Salvitti Chiara | Zendy; de Petris Giulia | Zendy

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Vanadium Hydroxide Cluster Ions in the Gas Phase: Bond‐Forming Reactions of Doubly‐Charged Negative Ions by SO 2 ‐Promoted V−O Activation

Author(s) -

Troiani Anna,

Rosi Marzio,

Garzoli Stefania,

Salvitti Chiara,

de Petris Giulia

Publication year - 2017

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201702165

Subject(s) - hydroxide , reactivity (psychology) , vanadium , ion , chemistry , cluster (spacecraft) , sulfur , gas phase , inorganic chemistry , phase (matter) , organic chemistry , medicine , alternative medicine , pathology , computer science , programming language

The gas‐phase reactivity of doubly‐charged vanadium hydroxides anions with SO 2 has been studied by experimental and computational methods. The obtained results highlight the role of sulfur dioxide in promoting unprecedented bond‐forming reactions, which produce singly‐charged products by breaking the V x O y skeleton or a terminal V−O bond.

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