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Inside Back Cover: Adamantylidene Addition to M 3 N@ I h ‐C 80 (M=Sc, Lu) and Sc 3 N@ D 5 h ‐C 80 : Synthesis and Crystallographic Characterization of the [5,6]‐Open and [6,6]‐Open Adducts (Chem. Eur. J. 27/2017)
Author(s) -
Yamada Michio,
Abe Tsuneyuki,
Saito Chiharu,
Yamazaki Toshiki,
Sato Satoru,
Mizorogi Naomi,
Slanina Zdenek,
Uhlík Filip,
Suzuki Mitsuaki,
Maeda Yutaka,
Lian Yongfu,
Lu Xing,
Olmstead Marilyn M.,
Balch Alan L.,
Nagase Shigeru,
Akasaka Takeshi
Publication year - 2017
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201700762
Subject(s) - crystallography , chemistry , adduct , cover (algebra) , atom (system on chip) , stereochemistry , combinatorics , mathematics , organic chemistry , computer science , embedded system , mechanical engineering , engineering
Adamantylidene (Ad) additions to endofullerenes M 3 N@ I h ‐C 80 (M=Sc, Lu) and Sc 3 N@ D 5h ‐C 80 are described. Notably, two Ad added bis‐adducts of Lu 3 N@ I h ‐C 80 were obtained, of which the structure of one isomer was determined by X‐ray crystallography. The experiments showed that the second Ad addition took place at a position close to an internal Lu atom, thus indicating that the regiochemistry of exohedral additions is influenced by the encaged cluster. More information can be found in the Full Paper by M. M. Olmstead, A. L. Balch, S. Nagase, T. Akasaka et al. on page 6552 ff.