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Inside Cover: Dimensionally Controlled Assembly of an External Stimuli‐Responsive [Co 2 Fe 2 ] Complex into Supramolecular Hydrogen‐Bonded Networks (Chem. Eur. J. 22/2017)
Author(s) -
Sekine Yoshihiro,
Nihei Masayuki,
Oshio Hiroki
Publication year - 2017
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201700625
Subject(s) - supramolecular chemistry , hydrogen bond , intramolecular force , cover (algebra) , honeycomb , hydrogen , materials science , self assembly , nanotechnology , crystallography , chemical physics , chemistry , stereochemistry , molecule , engineering , crystal structure , mechanical engineering , organic chemistry , composite material
Dimensionally controlled assembly of stimuli‐responsive [Co 2 Fe 2 ] complexes through directional hydrogen bonds is useful for the construction of multiple stable systems. In this work the formation of 1D chain and 2D honeycomb networks of [Co 2 Fe 2 ] by structure‐directing hydrogen‐bond donors, and the alteration of hydrogen‐bonding interactions coupled to intramolecular electron transfers, plays a key role in stabilizing the intermediate phases. More information can be found in the Communication by M. Nihei, H. Oshio, and Y. Sekine on page 5193 ff.