The Versatile Behavior of Platinum Alkyne Complexes towards XeF 2 : Formation of Fluorovinyl and Fluorido Complexes | Zendy

Berger Josefine | Zendy; Braun Thomas | Zendy; Ahrens Theresia | Zendy; Kläring Paul | Zendy; Laubenstein Reik | Zendy; BraunCula Beatrice | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

The Versatile Behavior of Platinum Alkyne Complexes towards XeF 2 : Formation of Fluorovinyl and Fluorido Complexes

Author(s) -

Berger Josefine,

Braun Thomas,

Ahrens Theresia,

Kläring Paul,

Laubenstein Reik,

BraunCula Beatrice

Publication year - 2017

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201700403

Subject(s) - platinum , ligand (biochemistry) , chelation , chemistry , electrophile , alkyne , combinatorial chemistry , stereochemistry , polymer chemistry , organic chemistry , catalysis , receptor , biochemistry

Reactions of platinum(0) tolane complexes, bearing a chelating ligand with P and N donor atoms, with the electrophilic fluorinating agent XeF 2 give facile access to platinum(II) β‐fluorovinyl fluorido complexes. A series of new platinum(II) β‐fluorovinyl complexes have been synthesized and were structurally characterized. Further oxidation with XeF 2 led to ortho ‐metalated platinum(IV) fluorido compounds. Additional reactions of platinum(0) tolane complexes, bearing a chelating P,P donor ligand, with XeF 2 led to a variety of fluorido and fluorovinyl complexes.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research