Premium
The Versatile Behavior of Platinum Alkyne Complexes towards XeF 2 : Formation of Fluorovinyl and Fluorido Complexes
Author(s) -
Berger Josefine,
Braun Thomas,
Ahrens Theresia,
Kläring Paul,
Laubenstein Reik,
BraunCula Beatrice
Publication year - 2017
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201700403
Subject(s) - platinum , ligand (biochemistry) , chelation , chemistry , electrophile , alkyne , combinatorial chemistry , stereochemistry , polymer chemistry , organic chemistry , catalysis , receptor , biochemistry
Reactions of platinum(0) tolane complexes, bearing a chelating ligand with P and N donor atoms, with the electrophilic fluorinating agent XeF 2 give facile access to platinum(II) β‐fluorovinyl fluorido complexes. A series of new platinum(II) β‐fluorovinyl complexes have been synthesized and were structurally characterized. Further oxidation with XeF 2 led to ortho ‐metalated platinum(IV) fluorido compounds. Additional reactions of platinum(0) tolane complexes, bearing a chelating P,P donor ligand, with XeF 2 led to a variety of fluorido and fluorovinyl complexes.