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Frontispiece: Copper(II) and Zinc(II) Complexes of Conformationally Constrained Polyazamacrocycles as Efficient Catalysts for RNA Model Substrate Cleavage in Aqueous Solution at Physiological pH
Author(s) -
Bím Daniel,
Svobodová Eva,
Eigner Václav,
Rulíšek Lubomír,
Hodačová Jana
Publication year - 2016
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201683062
Subject(s) - aqueous solution , zinc , catalysis , chemistry , cleavage (geology) , copper , substrate (aquarium) , stereochemistry , polymer chemistry , rna , bond cleavage , combinatorial chemistry , organic chemistry , materials science , biochemistry , biology , ecology , fracture (geology) , gene , composite material
Macrocyclic Ligands The catalytic activity of mono‐ and dinuclear copper(II) and zinc(II) complexes of conformationally constrained polyazamacrocycles towards cleavage of the P−O bond in the RNA model substrate 2‐hydroxypropyl‐4‐nitrophenylphosphate (HPNP) in aqueous solution at pH 7 are presented. For more details, see the Full Paper by L. Rulíšek, J. Hodačová et al. on page 10426 ff.