Frontispiece: Reactivity Studies on a Diazadiphosphapentalene | Zendy

Cui Jingjing | Zendy; Li Yongxin | Zendy; Ganguly Rakesh | Zendy; Kinjo Rei | Zendy

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Frontispiece: Reactivity Studies on a Diazadiphosphapentalene

Author(s) -

Cui Jingjing,

Li Yongxin,

Ganguly Rakesh,

Kinjo Rei

Publication year - 2016

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Reports

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201682962

Subject(s) - reactivity (psychology) , electrophile , photoisomerization , chemistry , derivative (finance) , cleavage (geology) , borane , ammonia borane , lewis acids and bases , ammonia , boranes , aryl , stereochemistry , medicinal chemistry , organic chemistry , materials science , catalysis , alkyl , isomerization , boron , medicine , alternative medicine , pathology , hydrogen production , fracture (geology) , financial economics , economics , composite material

Organophosphorus Compounds Diverse reactivity of diazadiphosphapentalene towards various substrates has been demonstrated. Diazadiphosphapentalene readily activates ammonia–borane proceeded concomitant with the cleavage of the P−N bond, while electrophiles and Lewis acids coordinate to one of the two P atoms in diazadiphosphapentalene. Photoisomerization of diazadiphosphapentalene affords a novel diazadiphosphapentalene derivative. For more details see the Full Paper by R. Kinjo et al. on page 9976 ff.

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