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Frontispiece: Reactivity Studies on a Diazadiphosphapentalene
Author(s) -
Cui Jingjing,
Li Yongxin,
Ganguly Rakesh,
Kinjo Rei
Publication year - 2016
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201682962
Subject(s) - reactivity (psychology) , electrophile , photoisomerization , chemistry , derivative (finance) , cleavage (geology) , borane , ammonia borane , lewis acids and bases , ammonia , boranes , aryl , stereochemistry , medicinal chemistry , organic chemistry , materials science , catalysis , alkyl , isomerization , boron , medicine , alternative medicine , pathology , hydrogen production , fracture (geology) , financial economics , economics , composite material
Organophosphorus Compounds Diverse reactivity of diazadiphosphapentalene towards various substrates has been demonstrated. Diazadiphosphapentalene readily activates ammonia–borane proceeded concomitant with the cleavage of the P−N bond, while electrophiles and Lewis acids coordinate to one of the two P atoms in diazadiphosphapentalene. Photoisomerization of diazadiphosphapentalene affords a novel diazadiphosphapentalene derivative. For more details see the Full Paper by R. Kinjo et al. on page 9976 ff.