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Frontispiece: A Two‐Component Alkyne Metathesis Catalyst System with an Improved Substrate Scope and Functional Group Tolerance: Development and Applications to Natural Product Synthesis
Author(s) -
Schaubach Sebastian,
Gebauer Konrad,
Ungeheuer Felix,
Hoffmeister Laura,
Ilg Marina K.,
Wirtz Conny,
Fürstner Alois
Publication year - 2016
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201682562
Subject(s) - functional group , silanol , scope (computer science) , catalysis , metathesis , natural product , molybdenum , substrate (aquarium) , chemistry , stereochemistry , biology , computer science , organic chemistry , programming language , ecology , polymer , polymerization
Natural Products How the massive trunk of reactive molybdenum alkylidyne complexes divides into several fertile branches of catalyst families which ultimately carry ripe fruit is described in the Full Paper by A. Fürstner et al. on page 8494 ff. The synergy between the molybdenum core and tridentate silanol ligands ensures high activities as well as functional group tolerance.