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Frontispiece: Highly Stable Mesoporous Zirconium Porphyrinic Frameworks with Distinct Flexibility
Author(s) -
Xu Lei,
Luo YanPing,
Sun Lin,
Xu Yan,
Cai ZhongSheng,
Fang Min,
Yuan RongXin,
Du HongBin
Publication year - 2016
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201681862
Subject(s) - porphyrin , metal organic framework , zirconium , linker , mesoporous material , materials science , flexibility (engineering) , amination , metal , catalysis , nanotechnology , chemistry , computer science , photochemistry , organic chemistry , adsorption , statistics , mathematics , operating system , metallurgy
Metal–Organic Frameworks Metal–porphyrinic frameworks (MPFs), which contain (metallo)porphyrin‐decorated ligands as linkers, are a subclass of metal–organic frameworks (MOFs). In their Full Paper on page 6268 ff., M. Fang and H. B. Du et al. describe the construction of a MPF (denoted as NUPF‐1) with an unprecedented interpenetrating scu net from a new porphyrin linker and a Zr 6 O 8 unit. NUPF‐1 exhibits not only remarkable chemical and thermal stabilities, but also a distinct structural flexibility and can be used as a heterogeneous catalyst for intermolecular C(sp 3 )−H amination after post‐metallization with [Ru 3 (CO) 12 ].
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