Premium
Inside Cover: Selective Heterogeneous C−H Activation/Halogenation Reactions Catalyzed by Pd@MOF Nanocomposites (Chem. Eur. J. 11/2016)
Author(s) -
Pascanu Vlad,
Carson Fabian,
Solano Marta Vico,
Su Jie,
Zou Xiaodong,
Johansson Magnus J.,
MartínMatute Belén
Publication year - 2016
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201681102
Subject(s) - halogenation , catalysis , palladium , selectivity , chemistry , nanocomposite , reaction conditions , cover (algebra) , combinatorial chemistry , metal organic framework , medicinal chemistry , organic chemistry , nanotechnology , materials science , mechanical engineering , engineering , adsorption
The engaging prospect of mild and selective C−H activation has attracted many families of catalysts to join this quest. Metal‐organic frameworks (MOFs) may play one of the leading roles in the story. Small and finely dispersed palladium nanoparticles supported in MOFs catalyze the halogenation of aromatic C−H bonds efficiently and under some of the mildest conditions reported to date. Furthermore, subtle changes in the reaction conditions results in high control over the selectivity. More information can be found in the Full Paper by B. Martín‐Matute et al. on page 3729 ff.