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Metal–Organic‐Framework‐Derived Carbons: Applications as Solid‐Base Catalyst and Support for Pd Nanoparticles in Tandem Catalysis
Author(s) -
Li Xinle,
Zhang Biying,
Fang Yuhui,
Sun Weijun,
Qi Zhiyuan,
Pei Yuchen,
Qi Shuyan,
Yuan Pengyu,
Luan Xuechen,
Goh Tian Wei,
Huang Wenyu
Publication year - 2017
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201605852
Subject(s) - knoevenagel condensation , catalysis , metal organic framework , pyrolysis , nanoparticle , lewis acids and bases , materials science , tandem , porosity , metal , chemistry , chemical engineering , organic chemistry , nanotechnology , adsorption , composite material , engineering
The facile pyrolysis of a bipyridyl metal‐organic framework, MOF‐253, produces N‐doped porous carbons (Cz‐MOF‐253), which exhibit excellent catalytic activity in the Knoevenagel condensation reaction and outperform other nitrogen‐containing MOF‐derived carbons. More importantly, by virtue of their high Lewis basicity and porous nature, Cz‐MOF‐253‐supported Pd nanoparticles (Pd/Cz‐MOF‐253‐800) show excellent performance in a one‐pot sequential Knoevenagel condensation‐hydrogenation reaction.