Lithium Aryloxide Thin Films with Guest‐Induced Structural Transformation by ALD/MLD | Zendy

Nisula Mikko | Zendy; Linnera Jarno | Zendy; Karttunen Antti J. | Zendy; Karppinen Maarit | Zendy

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Lithium Aryloxide Thin Films with Guest‐Induced Structural Transformation by ALD/MLD

Author(s) -

Nisula Mikko,

Linnera Jarno,

Karttunen Antti J.,

Karppinen Maarit

Publication year - 2017

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201605816

Subject(s) - lithium (medication) , transformation (genetics) , chemistry , materials science , chemical engineering , medicine , biochemistry , engineering , gene

Crystalline Li–organic thin films are grown with the atomic/molecular layer deposition (ALD/MLD) technique from lithium hexamethyldisilazide and hydroquinone. The as‐deposited films are found to undergo a reversible structural transformation upon exposure to ambient humid air. According to density functional theory calculations, the guest‐induced transformation may be related to an unsaturated Li site in the crystal structure.

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