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Inside Cover: Immobilizing Molecular Metal Dithiolene–Diamine Complexes on 2D Metal–Organic Frameworks for Electrocatalytic H 2 Production (Chem. Eur. J. 10/2017)
Author(s) -
Dong Renhao,
Zheng Zhikun,
Tranca Diana C.,
Zhang Jian,
Chandrasekhar Naisa,
Liu Shaohua,
Zhuang Xiaodong,
Seifert Gotthard,
Feng Xinliang
Publication year - 2017
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201605730
Subject(s) - diamine , metal , metal organic framework , catalysis , carbon fibers , cover (algebra) , materials science , electrode , chemistry , inorganic chemistry , polymer chemistry , organic chemistry , metallurgy , composite number , mechanical engineering , adsorption , engineering , composite material
Two‐dimensional metal–organic framework (MOF) sheets were synthesized by incorporation of the molecular metal dithiolene–diamine (MS 2 N 2 , M=Co and Ni), metal bis(dithiolene) (MS 4 ), and metal bis(diamine) (MN 4 ) complexes. 2D MOFs were applied as model carbon‐rich electrocatalysts for the hydrogen evolution reaction in water, and these studies provided an in‐depth understanding of the catalytic active sites, thus paving the way for the future development of metal complexes in carbon‐rich electrode materials for energy generation. More information can be found in the Communication by G. Seifert and X. Feng et al. on page 2255 ff.