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Cationic [(Iminophosphine)Nickel(Allyl)] + Complexes as the First Example of Nickel Catalysts for Direct Hydroamination of Allenes
Author(s) -
Tafazolian Hosein,
Schmidt Joseph A. R.
Publication year - 2017
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201605611
Subject(s) - hydroamination , cationic polymerization , nickel , catalysis , chemistry , organic chemistry
The first example of nickel‐catalyzed hydroamination of allenes is reported. The new cationic [(3‐iminophosphine)nickel(allyl)] + catalysts have been fully characterized and act regioselectively in the catalytic hydroamination of allenes with secondary amines at room temperature.