Isolation of a Reactive Cyclopropane Intermediate via a Unique Catalyst‐Free Spontaneous Cyclopropanation Step at 0 °C | Zendy

Braunschweig Holger | Zendy; Dewhurst Rian D. | Zendy; Ewing William C. | Zendy; KuntzeFechner Maximilian W. | Zendy; Schäfer Marius | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Isolation of a Reactive Cyclopropane Intermediate via a Unique Catalyst‐Free Spontaneous Cyclopropanation Step at 0 °C

Author(s) -

Braunschweig Holger,

Dewhurst Rian D.,

Ewing William C.,

KuntzeFechner Maximilian W.,

Schäfer Marius

Publication year - 2017

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201605514

Subject(s) - cyclopropanation , cyclopropane , catalysis , cascade , bicyclic molecule , chemistry , isolation (microbiology) , photochemistry , stereochemistry , organic chemistry , ring (chemistry) , biology , chromatography , microbiology and biotechnology

A remarkably mild, catalyst‐free cyclopropanation reaction is confirmed by low‐temperature isolation of a fused bicyclic cyclopropane intermediate. This intermediate is one of two that were isolated and fully characterised in a three‐step temperature‐controllable reaction cascade.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research