Fabrication of Holey Graphene: Catalytic Oxidation by Metalloporphyrin‐Based Covalent Organic Framework Immobilized on Highly Ordered Pyrolytic Graphite | Zendy

Seo Wanji | Zendy; White David L. | Zendy; Star Alexander | Zendy

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Fabrication of Holey Graphene: Catalytic Oxidation by Metalloporphyrin‐Based Covalent Organic Framework Immobilized on Highly Ordered Pyrolytic Graphite

Author(s) -

Seo Wanji,

White David L.,

Star Alexander

Publication year - 2017

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201605488

Subject(s) - pyrolytic carbon , graphene , highly oriented pyrolytic graphite , covalent bond , graphite , exfoliation joint , catalysis , porphyrin , bifunctional , materials science , catalytic oxidation , fabrication , chemical engineering , covalent organic framework , nanotechnology , organic chemistry , chemistry , composite material , pyrolysis , medicine , alternative medicine , pathology , engineering

We report a facile chemical method for fabricating holey graphene by catalytic oxidation of highly ordered pyrolytic graphite (HOPG) using an Fe III porphyrin complex‐based covalent organic framework (COF) as a bifunctional surface catalyst–template. We demonstrate regular hole formation after oxidation with H 2 O 2 and NaOCl, COF removal, and HOPG exfoliation.

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