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Back Cover: Two Independent Orthogonal Stereomutations at a Single Asymmetric Center: A Narcissistic Couple (Chem. Eur. J. 10/2017)
Author(s) -
GillickHealy Malachi W.,
Jennings Elizabeth V.,
MüllerBunz Helge,
Ortin Yannick,
Nikitin Kirill,
Gilheany Declan G.
Publication year - 2017
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201605449
Subject(s) - cover (algebra) , center (category theory) , chemistry , janus , stereochemistry , crystallography , materials science , nanotechnology , engineering , mechanical engineering
Four‐faced Janus , the god of transitions, now permits interconversion of two mirror images of a P‐phenyl‐phosphabarbaralane via two orthogonal mechanisms at the same asymmetric center; a Walden‐type inversion of a phosphonium salt and a Cope rearrangement of its caged cyclic hydrocarbon skeleton. More information can be found in the Full Paper by K. Nikitin and D. G. Gilheany et al. on page 2332 ff.