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Cover Picture: Detailed Structural Analysis of a Self‐Assembled Vesicular Amphiphilic NCN‐Pincer Palladium Complex by Using Wide‐Angle X‐Ray Scattering and Molecular Dynamics Calculations (Chem. Eur. J. 6/2017)
Author(s) -
Hamasaka Go,
Muto Tsubasa,
Andoh Yoshimichi,
Fujimoto Kazushi,
Kato Kenichi,
Takata Masaki,
Okazaki Susumu,
Uozumi Yasuhiro
Publication year - 2017
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201605178
Subject(s) - bilayer , pincer movement , chemistry , vesicle , palladium , small angle x ray scattering , amphiphile , molecular dynamics , scattering , okazaki fragments , catalysis , crystallography , chemical physics , membrane , computational chemistry , organic chemistry , copolymer , physics , polymer , optics , biochemistry , eukaryotic dna replication , dna repair , gene
An amphiphilic NCN‐pincer palladium complex constructs bilayer vesicles in a self‐assembling manner, through which the complex gains its catalytic activity in water, for example, in a Miyaura–Michael reaction. Wide‐angle X‐ray scattering experiments and all‐atomistic molecular dynamics calculations were performed to elucidate the detailed structure and reacting behavior of the bilayer catalytic vesicles. More information can be found in the Full Paper by S. Okazaki and Y. Uozumi et al. on page 1291 ff.