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Pentafluoroethyl Bismuth Compounds
Author(s) -
Solyntjes Sven,
Bader Julia,
Neumann Beate,
Stammler HansGeorg,
Ignat'ev Nikolai,
Hoge Berthold
Publication year - 2017
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201604910
Subject(s) - bismuth , tris , crystallography , chemistry , transition metal , diffraction , inorganic chemistry , organic chemistry , physics , optics , biochemistry , catalysis
Abstract A series of tris‐, bis‐, and mono(pentafluoroethyl)bismuthanes of the type (C 2 F 5 ) n BiX 3– n (X=F, Cl, Br, I) and transition metal complexes are accessible by a sophisticated pentafluoroethylation protocol. Chemical properties, induced by the strongly electron‐withdrawing character of C 2 F 5 groups, are described for representative examples. Moreover, the first molecular structures of perfluoroalkyl bismuthanes and bismuthates obtained by X‐ray diffraction are presented.